Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex.
نویسندگان
چکیده
A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3) to afford the corresponding dimolybdenum-dinitrogen complex together with the formation of molecular dihydrogen. This reaction proceeds via the ligand exchange of the coordinated dihydrogen generated in situ with molecular dinitrogen.
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Institute of Engineering Innovation, School Yayoi, Bunkyo-ku, Tokyo 113-8656, Japan. E Elements Strategy Initiative for Catalysts Nishikyo-ku, Kyoto 615-8520, Japan Institute for Materials Chemistry and Engin for Molecular System, Kyushu University, Ni [email protected] † Electronic supplementary information ( For ESI and crystallographic data in CI 10.1039/c5sc00545k Cite this: C...
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 95 شماره
صفحات -
تاریخ انتشار 2013